Here's one way, that only requires one magic line to be added to the basic figure: the short black horizontal line is contructed at right angles to the mirror on the right, where the red light beam reflects. We've also extended one of the red lines through the mirror: this is geometry, not physics. Five angles are labeled, A through E. We're going to show, step by step, that they're all equal. If you mouseover the pointing hands below, that step is highlit.
First, angle A equals angle B, because that's the rule for reflection. Next, angle C equals angle D, for the same reason.
Now the trickier one, E = C. You need to remember some geometry for this one.
In particular, when you have two parallel lines and a third line crossing
them, the angles formed are equal. And the reverse: if the angles are
equal, the lines are parallel. The two horizontal black lines in the big figure are parallel,
since they form equal angles with the vertical black line. (Both are
right angles, since we defined them that way...this is where the fact
that the mirrors are at right angles to each other is used)
So all the angles are equal, A = B = C = D = E.
We didn't use any special property of the angle A, so the incoming and
outgoing light is parallel at any value of angle A. We did use
the fact that the mirrors are perpendicular, so this proof is valid only
for a 90 degree corner reflector.